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Carbon-13 n.m.r. spectra are reported as a function of pH for 3,7-diazanonane-1,9-diamine (dadn), for mixtures of dadn or 1,2-diaminoethane (en) and zinc nitrate, and for mixtures of zinc and dadn with en, 1,3-diaminopropane (pn), acetate, glycine (gly), and -alanine (ala). The pH profiles have been analysed by com

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